Materials Chemistry and Physics
The corrosion behaviour of CortenA weathering steel has been investigated using a laboratory accelerated test that involved cyclic wet/dry conditions in Qinghai salt lake water diluted 30 times The characteristics of the rust layers on tested samples were observed by SEM and EPMA analyzed by IRS and XRD and studied by polarization and EIS measurements The weight loss was almost linear indicating that the rust layer had no retarding effect on the corrosion process The crystalline components of the rust layers consisted primarily of beta-FeOOH magnetite (Fe(3)O(4)) and gamma-FeOOH As the corrosion proceeded the amount of beta-FeOOH decreased while that of magnetite and gamma-FeOOH increased XRD EDAX and EPMA indicated that the complex corrosion products magnesioferrite (MgFe(2)O(4)) and iowaite (Mg(4)Fe(OH)(8)OCl 4H(2)O) probably existed in the rust layer in which case they will have had an important Influence on the protectiveness of the rust layer The results of electrochemical measurements showed that the rust layer exhibited high reduction reactivity which facilitated the corrosion of weathering steel in the wetting process The large rust capacitance and small rust resistance indicated that the rust layer had a loose and porous structure which provided poor protection (c) 2010 Elsevier B V All rights reserved
关键词:
Elements;Corrosion test;Electrochemical techniques;Electron probe;low-alloy steels;atmospheric corrosion;carbon-steel;electrochemical;impedance;room-temperature;rust layers;iron;mechanism;products;environment
